Chemical Biochemical and Engineering Thermodynamics 5th edition by Stanley Sandler – Ebook PDF Instant Download/Delivery: 1119321286 , 9781119321286
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ISBN 10: 1119321286
ISBN 13: 9781119321286
Author: Stanley Sandler
In this newly revised 5th Edition of Chemical and Engineering Thermodynamics, Sandler presents a modern, applied approach to chemical thermodynamics and provides sufficient detail to develop a solid understanding of the key principles in the field. The text confronts current information on environmental and safety issues and how chemical engineering principles apply in biochemical engineering, bio-technology, polymers, and solid-state-processing. This book is appropriate for the undergraduate and graduate level courses.
Chemical Biochemical and Engineering Thermodynamics 5th Table of contents:
CHAPTER 1: INTRODUCTION
1.1 THE CENTRAL PROBLEMS OF THERMODYNAMICS
1.2 A SYSTEM OF UNITS
1.3 THE EQUILIBRIUM STATE
1.4 PRESSURE, TEMPERATURE, AND EQUILIBRIUM
1.5 HEAT, WORK, AND THE CONSERVATION OF ENERGY
1.6 SPECIFICATION OF THE EQUILIBRIUM STATE; INTENSIVE AND EXTENSIVE VARIABLES; EQUATIONS OF STATE
1.7 A SUMMARY OF IMPORTANT EXPERIMENTAL OBSERVATIONS
1.8 A COMMENT ON THE DEVELOPMENT OF THERMODYNAMICS
PROBLEMS
CHAPTER 2: CONSERVATION OF MASS
2.1 A GENERAL BALANCE EQUATION AND CONSERVED QUANTITIES
2.2 CONSERVATION OF MASS FOR A PURE FLUID
2.3 THE MASS BALANCE EQUATIONS FOR A MULTICOMPONENT SYSTEM WITH A CHEMICAL REACTION
2.4 THE MICROSCOPIC MASS BALANCE EQUATIONS IN THERMODYNAMICS AND FLUID MECHANICS
PROBLEMS
CHAPTER 3: CONSERVATION OF ENERGY
3.1 CONSERVATION OF ENERGY
3.2 SEVERAL EXAMPLES OF USING THE ENERGY BALANCE
3.3 THE THERMODYNAMIC PROPERTIES OF MATTER
3.4 APPLICATIONS OF THE MASS AND ENERGY BALANCES
3.5 CONSERVATION OF MOMENTUM
PROBLEMS
CHAPTER 4: ENTROPY: AN ADDITIONAL BALANCE EQUATION
4.1 ENTROPY: A NEW CONCEPT
4.2 THE ENTROPY BALANCE AND REVERSIBILITY
4.3 HEAT, WORK, ENGINES, AND ENTROPY
4.4 ENTROPY CHANGES OF MATTER
4.5 APPLICATIONS OF THE ENTROPY BALANCE
4.6 AVAILABILITY AND THE MAXIMUM USEFUL SHAFT WORK THAT CAN BE OBTAINED IN A CHANGE OF STATE
4.7 THE MICROSCOPIC ENTROPY BALANCE (OPTIONAL)
PROBLEMS
CHAPTER 5: LIQUEFACTION, POWER CYCLES, AND EXPLOSIONS
5.1 LIQUEFACTION
5.2 POWER GENERATION AND REFRIGERATION CYCLES
5.3 THERMODYNAMIC EFFICIENCIES
5.4 THE THERMODYNAMICS OF MECHANICAL EXPLOSIONS
PROBLEMS
CHAPTER 6: THE THERMODYNAMIC PROPERTIES OF REAL SUBSTANCES
6.1 SOME MATHEMATICAL PRELIMINARIES
6.2 THE EVALUATION OF THERMODYNAMIC PARTIAL DERIVATIVES
6.3 THE IDEAL GAS AND ABSOLUTE TEMPERATURE SCALES
6.4 THE EVALUATION OF CHANGES IN THE THERMODYNAMIC PROPERTIES OF REAL SUBSTANCES ACCOMPANYING A CHANGE OF STATE
6.5 AN EXAMPLE INVOLVING THE CHANGE OF STATE OF A REAL GAS
6.6 THE PRINCIPLE OF CORRESPONDING STATES
6.7 GENERALIZED EQUATIONS OF STATE
6.8 THE THIRD LAW OF THERMODYNAMICS
6.9 ESTIMATION METHODS FOR CRITICAL AND OTHER PROPERTIES
6.10 SONIC VELOCITY
6.11 MORE ABOUT THERMODYNAMIC PARTIAL DERIVATIVES (OPTIONAL)
PROBLEMS
CHAPTER 7: EQUILIBRIUM AND STABILITY IN ONE‐COMPONENT SYSTEMS
7.1 THE CRITERIA FOR EQUILIBRIUM
7.2 STABILITY OF THERMODYNAMIC SYSTEMS
7.3 PHASE EQUILIBRIA: APPLICATION OF THE EQUILIBRIUM AND STABILITY CRITERIA TO THE EQUATION OF STATE
7.4 THE MOLAR GIBBS ENERGY AND FUGACITY OF A PURE COMPONENT
7.5 THE CALCULATION OF PURE FLUID‐PHASE EQUILIBRIUM: THE COMPUTATION OF VAPOR PRESSURE FROM AN EQUATION OF STATE
7.6 SPECIFICATION OF THE EQUILIBRIUM THERMODYNAMIC STATE OF A SYSTEM OF SEVERAL PHASES: THE GIBBS PHASE RULE FOR A ONE‐COMPONENT SYSTEM
7.7 THERMODYNAMIC PROPERTIES OF PHASE TRANSITIONS
7.8 THERMODYNAMIC PROPERTIES OF SMALL SYSTEMS, OR WHY SUBCOOLING AND SUPERHEATING OCCUR
PROBLEMS
CHAPTER 8: THE THERMODYNAMICS OF MULTICOMPONENT MIXTURES
8.1 THE THERMODYNAMIC DESCRIPTION OF MIXTURES
8.2 THE PARTIAL MOLAR GIBBS ENERGY AND THE GENERALIZED GIBBS-DUHEM EQUATION
8.3 A NOTATION FOR CHEMICAL REACTIONS
8.4 THE EQUATIONS OF CHANGE FOR A MULTICOMPONENT SYSTEM
8.5 THE HEAT OF REACTION AND A CONVENTION FOR THE THERMODYNAMIC PROPERTIES OF REACTING MIXTURES
8.6 THE EXPERIMENTAL DETERMINATION OF THE PARTIAL MOLAR VOLUME AND ENTHALPY
8.7 CRITERIA FOR PHASE EQUILIBRIUM IN MULTICOMPONENT SYSTEMS
8.8 CRITERIA FOR CHEMICAL EQUILIBRIUM, AND COMBINED CHEMICAL AND PHASE EQUILIBRIUM
8.9 SPECIFICATION OF THE EQUILIBRIUM THERMODYNAMIC STATE OF A MULTICOMPONENT, MULTIPHASE SYSTEM; THE GIBBS PHASE RULE
8.10 A CONCLUDING REMARK
PROBLEMS
CHAPTER 9: ESTIMATION OF THE GIBBS ENERGY AND FUGACITY OF A COMPONENT IN A MIXTURE
9.1 THE IDEAL GAS MIXTURE
9.2 THE PARTIAL MOLAR GIBBS ENERGY AND FUGACITY
9.3 IDEAL MIXTURE AND EXCESS MIXTURE PROPERTIES
9.4 FUGACITY OF SPECIES IN GASEOUS, LIQUID, AND SOLID MIXTURES
9.5 SEVERAL CORRELATIVE LIQUID MIXTURE ACTIVITY COEFFICIENT MODELS
9.6 TWO PREDICTIVE ACTIVITY COEFFICIENT MODELS
9.7 FUGACITY OF SPECIES IN NONSIMPLE MIXTURES
9.8 SOME COMMENTS ON REFERENCE AND STANDARD STATES
9.9 COMBINED EQUATION-OF-STATE AND EXCESS GIBBS ENERGY MODEL
9.10 ELECTROLYTE SOLUTIONS
9.11 CHOOSING THE APPROPRIATE THERMODYNAMIC MODEL
APPENDIX A9.1 A STATISTICAL MECHANICAL INTERPRETATION OF THE ENTROPY OF MIXING IN AN IDEAL MIXTURE
APPENDIX A9.2 MULTICOMPONENT EXCESS GIBBS ENERGY (ACTIVITY COEFFICIENT) MODELS
APPENDIX A9.3 THE ACTIVITY COEFFICIENT OF A SOLVENT IN AN ELECTROLYTE SOLUTION
PROBLEMS
CHAPTER 10: VAPOR‐LIQUID EQUILIBRIUM IN MIXTURES
10.0 INTRODUCTION TO VAPOR‐LIQUID EQUILIBRIUM
10.1 VAPOR‐LIQUID EQUILIBRIUM IN IDEAL MIXTURES
PROBLEMS FOR SECTION 10.1
10.2 LOW‐PRESSURE VAPOR‐LIQUID EQUILIBRIUM IN NONIDEAL MIXTURES
PROBLEMS FOR SECTION 10.2
10.3 HIGH‐PRESSURE VAPOR‐LIQUID EQUILIBRIA USING EQUATIONS OF STATE (ϕ‐ϕ METHOD)
PROBLEMS FOR SECTION 10.3
CHAPTER 11: OTHER TYPES OF PHASE EQUILIBRIA IN FLUID MIXTURES
11.1 THE SOLUBILITY OF A GAS IN A LIQUID
PROBLEMS FOR SECTION 11.1
11.2 LIQUID-LIQUID EQUILIBRIUM
PROBLEMS FOR SECTION 11.2
11.3 VAPOR-LIQUID-LIQUID EQUILIBRIUM
PROBLEMS FOR SECTION 11.3
11.4 THE PARTITIONING OF A SOLUTE AMONG TWO COEXISTING LIQUID PHASES; THE DISTRIBUTION COEFFICIENT
PROBLEMS FOR SECTION 11.4
11.5 OSMOTIC EQUILIBRIUM AND OSMOTIC PRESSURE
PROBLEMS FOR SECTION 11.5
CHAPTER 12: MIXTURE PHASE EQUILIBRIA INVOLVING SOLIDS
12.1 THE SOLUBILITY OF A SOLID IN A LIQUID, GAS, OR SUPERCRITICAL FLUID
PROBLEMS FOR SECTION 12.1
12.2 PARTITIONING OF A SOLID SOLUTE BETWEEN TWO LIQUID PHASES
PROBLEM FOR SECTION 12.2
12.3 FREEZING-POINT DEPRESSION OF A SOLVENT DUE TO THE PRESENCE OF A SOLUTE; THE FREEZING POINT OF LIQUID MIXTURES
PROBLEMS FOR SECTION 12.3
12.4 PHASE BEHAVIOR OF SOLID MIXTURES
PROBLEMS FOR SECTION 12.4
12.5 THE PHASE BEHAVIOR MODELING OF CHEMICALS IN THE ENVIRONMENT
PROBLEMS FOR SECTION 12.5
12.6 PROCESS DESIGN AND PRODUCT DESIGN
PROBLEM FOR SECTION 12.6
12.7 CONCLUDING REMARKS ON PHASE EQUILIBRIA
CHAPTER 13: CHEMICAL EQUILIBRIUM
13.1 CHEMICAL EQUILIBRIUM IN A SINGLE-PHASE SYSTEM
13.2 HETEROGENEOUS CHEMICAL REACTIONS
13.3 CHEMICAL EQUILIBRIUM WHEN SEVERAL REACTIONS OCCUR IN A SINGLE PHASE
13.4 COMBINED CHEMICAL AND PHASE EQUILIBRIUM
13.5 IONIZATION AND THE ACIDITY OF SOLUTIONS
13.6 IONIZATION OF BIOCHEMICALS
13.7 PARTITIONING OF AMINO ACIDS AND PROTEINS BETWEEN TWO LIQUIDS
PROMLEMS
CHAPTER 14: THE BALANCE EQUATIONS FOR CHEMICAL REACTORS, AVAILABILITY, AND ELECTROCHEMISTRY
14.1 THE BALANCE EQUATIONS FOR A TANK-TYPE CHEMICAL REACTOR
14.2 THE BALANCE EQUATIONS FOR A TUBULAR REACTOR
14.3 OVERALL REACTOR BALANCE EQUATIONS AND THE ADIABATIC REACTION TEMPERATURE
14.4 THERMODYNAMICS OF CHEMICAL EXPLOSIONS
14.5 MAXIMUM USEFUL WORK AND AVAILABILITY IN CHEMICALLY REACTING SYSTEMS
14.6 INTRODUCTION TO ELECTROCHEMICAL PROCESSES
14.7 FUEL CELLS AND BATTERIES
PROBLEMS
CHAPTER 15: SOME ADDITIONAL BIOCHEMICAL APPLICATIONS OF THERMODYNAMICS
15.1 SOLUBILITIES OF WEAK ACIDS, WEAK BASES, AND AMINO ACIDS AS A FUNCTION OF pH
15.2 THE SOLUBILITY OF AMINO ACIDS AND PROTEINS AS A FUNCITON OF IONIC STRENGTH AND TEMPERATURE
15.3 BINDING OF A LIGAND TO A SUBSTRATE
15.4 SOME OTHER EXAMPLES OF BIOCHEMICAL REACTIONS
15.5 THE DENATURATION OF PROTEINS
15.6 COUPLED BIOCHEMICAL REACTIONS: THE ATP‐ADP ENERGY STORAGE AND DELIVERY MECHANISM
15.7 THERMODYNAMIC ANALYSIS OF FERMENTERS AND OTHER BIOREACTORS
15.8 GIBBS‐DONNAN EQUILIBRIUM AND MEMBRANE POTENTIALS
15.9 PROTEIN CONCENTRATION IN AN ULTRACENTRIFUGE
PROBLEMS
APPENDIX A: THERMODYNAMIC DATA
A.I CONVERSION FACTORS TO SI UNITS
A.II THE MOLAR HEAT CAPACITIES OF GASES IN THE IDEAL GAS (ZERO‐PRESSURE) STATE
A.III THE THERMODYNAMIC PROPERTIES OF WATER AND STEAM
A.IV ENTHALPIES AND GIBBS ENERGIES OF FORMATION
A.V HEATS OF COMBUSTION
APPENDIX B: BRIEF DESCRIPTIONS OF COMPUTER AIDS FOR USE WITH THIS BOOK—A MORE DETAILED DESCRIPTION OF THE PROGRAMS AND WORKSHEETS APPEAR ON THE WILEY WEBSITE FOR THIS BOOK
APPENDIX C: ASPEN ILLUSTRATION INPUT FILES. THESE ARE ON THE WEBSITE FOR THIS BOOK
APPENDIX D: ANSWERS TO SELECTED PROBLEMS
INDEX
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