Molecular Engineering Thermodynamics 1st editon by Juan de Pablo, Jay Schieber – Ebook PDF Instant Download/Delivery: 0521765625, 9780521765626
Full dowload Molecular Engineering Thermodynamics 1st editon after payment
Product details:
ISBN 10: 0521765625
ISBN 13: 9780521765626
Author: Juan J. de Pablo; Jay D. Schieber
Building up gradually from first principles, this unique introduction to modern thermodynamics integrates classical, statistical and molecular approaches and is especially designed to support students studying chemical and biochemical engineering. In addition to covering traditional problems in engineering thermodynamics in the context of biology and materials chemistry, students are also introduced to the thermodynamics of DNA, proteins, polymers and surfaces. It includes over 80 detailed worked examples, covering a broad range of scenarios such as fuel cell efficiency, DNA/protein binding, semiconductor manufacturing and polymer foaming, emphasizing the practical real-world applications of thermodynamic principles; more than 300 carefully tailored homework problems, designed to stretch and extend students’ understanding of key topics, accompanied by an online solution manual for instructors; and all the necessary mathematical background, plus resources summarizing commonly used symbols, useful equations of state, microscopic balances for open systems, and links to useful online tools and datasets.
Molecular Engineering Thermodynamics 1st Table of contents:
1. Introduction
1.1 Relevant questions for thermodynamics
1.2 Work and energy
Exercises
2. The postulates of thermodynamics
2.1 The postulational approach
2.2 The first law: energy conservation
2.3 Definition of heat
2.4 Equilibrium states
2.5 Entropy, the second law, and the fundamental relation
2.6 Definitions of temperature, pressure, and chemical potential
2.7 Temperature differences and heat flow
2.8 Pressure differences and volume changes
2.9 Thermodynamics in one dimension
Summary
Exercises
3. Generalized thermodynamic potentials
3.1 Legendre transforms
3.2 Extremum principles for the potentials
3.3 The Maxwell relations
3.4 The thermodynamic square
3.5 Second-order coefficients
3.6 Thermodynamic manipulations
3.7 One- and two-dimensional systems
3.7.1 A non-ideal rubber band
3.7.2 Unzipping DNA
3.7.3 Langmuir adsorption
Summary
Exercises
4. First applications of thermodynamics
4.1 Stability criteria
4.1.1 Entropy
4.1.2 Internal energy
4.1.3 Generalized potentials
4.2 Single-component vapor–liquid equilibrium
4.2.1 The spinodal curve of a van der Waals fluid
4.2.2 The binodal (or coexistence) curve of a van der Waals fluid
4.2.3 The general formulation
4.2.4 Approximations based on the Clapeyron equation
4.3 Crystallization of solids
4.4 Thermodynamic diagrams
4.4.1 Construction of fundamental relations from two equations of state for single-component systems
4.4.2 Residual properties
Summary
Exercises
5. Application to process design: flow systems
5.1 Macroscopic mass, energy, and entropy balances
5.1.1 The throttling process
5.1.2 Specifications for a turbine generator
5.1.3 Work requirements for a pump
5.1.4 The Ranque–Hilsch vortex tube
5.1.5 Fuel cells
5.2 Cycles
5.2.1 The Carnot cycle
5.2.2 The Rankine power cycle
5.2.3 The refrigeration cycle
Summary
Exercises
6. Statistical mechanics
6.1 Ensemble and time averages
6.2 The canonical ensemble
6.3 Ideal gases
6.3.1 A simple ideal gas
6.3.2 A general ideal gas
6.4 Langmuir adsorption
6.5 The grand canonical ensemble
6.6 An elastic strand
6.7 Fluctuations
Summary
Exercises
7. Molecular interactions
7.1 Ideal gases
7.2 Intermolecular interactions
7.2.1 The significance of “k[sub(B)]T”
7.2.2 Interactions at long distances
7.2.3 Interactions at short distances
7.2.4 Empirical potential-energy functions
7.2.5 Hydrogen bonds
7.3 Molecular simulations
7.4 The virial expansion
7.5 Equations of state for liquids
7.6 Experimental manifestations of intermolecular interactions
Conclusions
Exercises
8. Fugacity and vapor–liquid equilibrium
8.1 General equations of phase equilibria
8.2 Mixtures of ideal gases
8.3 Mixtures: partial molar properties
8.3.1 Definition of a partial molar property
8.3.2 General properties of partial molar quantities
8.3.3 Residual partial molar quantities
8.4 Fugacity
8.4.1 Definition of fugacity
8.4.2 Properties of fugacity
8.4.3 Estimating the fugacity of a pure vapor or liquid
8.5 Calculation of fugacity coefficients of mixtures from PVT equations of state
8.6 Fugacity in ideal or Lewis mixtures
8.6.1 Lewis mixing
8.6.2 Properties of Lewis (ideal) mixtures
8.6.3 A simple application of Lewis (ideal) mixing: Raoult’s law
8.7 Solubility of solids and liquids in compressed gases
8.7.1 Phase equilibria between a solid and a compressed gas
8.7.2 Phase equilibria between a liquid and a compressed gas
Summary
Exercises
9. Activity and equilibrium
9.1 Excess properties and activities
9.2 A summary of fugacity and activity
9.3 Correlations for partial molar excess Gibbs free energy
9.3.1 Simple binary systems
9.3.2 Thermodynamic consistency
9.4 Semi-theoretical expressions for activity coefficients
9.4.1 The van Laar equation
9.4.2 Wilson’s equation
9.4.3 The NRTL equation
9.4.4 The UNIQUAC model
9.5 Dilute mixtures: Henry’s constants
9.5.1 Measurement of activity coefficients
9.6 The blood–brain barrier
9.7 Partial miscibility
9.7.1 Thermodynamic stability
9.7.2 Liquid–liquid equilibria in ternary mixtures
9.7.3 Critical points
9.8 Simple free-energy models from statistical mechanics
9.8.1 Lewis mixing
9.8.2 The Margules model
9.8.3 Exact solution of the lattice model
Summary
Exercises
10. Reaction equilibrium
10.1 A simple picture: the reaction coordinate
10.2 Extent of reaction
10.3 The equilibrium criterion
10.4 The reaction equilibrium constant
10.5 Standard property changes
10.6 Estimating the equilibrium constant
10.7 Determination of equilibrium compositions
10.8 Enzymatic catalysis: the Michaelis–Menten model
10.9 Denaturation of DNA and polymerase chain reactions
10.9.1 Denaturation
10.9.2 Polymerase chain reaction
10.10 Statistical mechanics of reactions and denaturation
10.10.1 Stochastic fluctuations in reactions
10.10.2 DNA denaturation
Summary
Exercises
11. Thermodynamics of polymers
11.1 Solubility and miscibility of polymer solutions
11.2 Generalizations of the Flory–Huggins theory
11.2.1 The generalization of Qian et al.
11.2.2 The Sanchez–Lacombe equation of state
11.2.3 The BGY model
11.3 Block copolymers
11.4 Derivation of the Flory–Huggins theory
Summary
Exercises
12. Thermodynamics of surfaces
12.1 The interfacial tension of a planar interface
12.2 The Gibbs free energy of a surface phase and the Gibbs–Duhem relation
12.3 Curved interfaces
12.4 Solid–liquid interfaces: wetting
12.5 Capillary forces
12.6 Solid–gas interfaces: adsorption
12.7 The temperature dependence of surface tension
12.8 Interfaces in mixtures
12.8.1 Vapor–liquid interfaces
12.8.2 Monolayer formation on liquid surfaces
Summary
People also search for Molecular Engineering Thermodynamics 1st:
molecular thermodynamics
modern engineering thermodynamics pdf
modern engineering thermodynamics
introduction to molecular thermodynamics
Reviews
There are no reviews yet.